We present a new grid of model photospheres for the SDSS-III/APOGEE survey of stellar populations of the Galaxy, calculated using the ATLAS9 and MARCS codes. New opacity distribution functions were generated to calculate ATLAS9 model photospheres. MARCS models were calculated based on opacity sampling techniques. The metallicity ([M/H]) spans from -5 to 1.5 for ATLAS and -2.5 to 0.5 for MARCS models. There are three main differences with respect to previous ATLAS9 model grids: a new corrected H2O linelist, a wide range of carbon ([C/M]) and alpha element [alpha/M] variations, and solar reference abundances from Asplund et al. 2005. The added range of varying carbon and alpha element abundances also extends the previously calculated MARCS model grids. Altogether 1980 chemical compositions were used for the ATLAS9 grid, and 175 for the MARCS grid. Over 808 thousand ATLAS9 models were computed spanning temperatures from 3500K to 30000K and log g from 0 to 5, where larger temperatures only have high gravities. The MARCS models span from 3500K to 5500K, and log g from 0 to 5. All model atmospheres are publically available online.

We investigate the formation of CIII 4647-51-50 and CIII 5696 in the atmosphere of O stars to see if they can be reliably used for abundance determinations. We use atmosphere models computed with the code CMFGEN. The key physical ingredients explaining the formation of the CIII lines are extracted from comparisons of models with different stellar parameters and through examining rates controlling the level populations. The strength of CIII 5696 critically depends on UV CIII lines at 386, 574 and 884 A. These lines control the CIII 5696 upper and lower level population. CIII 884 plays a key role in late O stars where it drains the lower level of CIII 5696. CIII 386 and CIII 574 are more important at early spectral types. The overlap of these UV lines with FeIV 386.262, FeIV 574.232 and SV 884.531 influences the radiative transfer at 386, 574 and 884 A, and consequently affects the strength of CIII 5696. CIII 4650 is mainly controlled by the CIII 538 line which acts as a drain on its lower level. FeIV 538.057 interacts with CIII 538 and has an impact on the CIII 4650 profile. Low temperature dielectronic recombinations have a negligible effect on the line profiles. Given our current understanding of the stellar and wind properties of O stars, and in view of the present results, the determination of accurate carbon abundances from CIII 4647-51-50 and CIII 5696 is an extremely challenging task. Uncertainties lower than a factor of two on C/H determinations based only on these two sets of lines should be regarder as highly doubtful. Our results provide a possible explanation of the variability of CIII 4650 in Of?p stars.

This paper presents a first observational investigation of the faint Of?cp star NGC 1624-2, yielding important new constraints on its spectral and physical characteristics, rotation, magnetic field strength, X-ray emission and magnetospheric properties. Modeling the spectrum and spectral energy distribution, we conclude that NGC 1624-2 is a main sequence star of mass M {\simeq} 30 M{\odot}, and infer an effective temperature of 35 {\pm} 2 kK and log g = 4.0 {\pm} 0.2. Based on an extensive time series of optical spectral observations we report significant variability of a large number of spectral lines, and infer a unique period of 157.99 {\pm} 0.94 d which we interpret as the rotational period of the star. We report the detection of a very strong - 5.35 {\pm} 0.5 kG - longitudinal magnetic field , coupled with probable Zeeman splitting of Stokes I profiles of metal lines confirming a surface field modulus of 14 {\pm} 1 kG, consistent with a surface dipole of polar strength >~ 20 kG. This is the largest magnetic field ever detected in an O-type star, and the first report of Zeeman splitting of Stokes I profiles in such an object. We also report the detection of reversed Stokes V profiles associated with weak, high-excitation emission lines of O iii, which we propose may form in the close magnetosphere of the star. We analyze archival Chandra ACIS-I X-ray data, inferring a very hard spectrum with an X-ray efficiency log Lx/Lbol = -6.4, a factor of 4 larger than the canonical value for O-type stars and comparable to that of the young magnetic O-type star {\theta}1 Ori C and other Of?p stars. Finally, we examine the probable magnetospheric properties of the star, reporting in particular very strong magnetic confinement of the stellar wind, with {\eta}* {\simeq} 1.5 {\times} 10^4, and a very large Alfven radius, RAlf = 11.4 R*.

We present a novel chemical database for gas-phase astrochemistry. Named the KInetic Database for Astrochemistry (KIDA), this database consists of gas-phase reactions with rate coefficients and uncertainties that will be vetted to the greatest extent possible. Submissions of measured and calculated rate coefficients are welcome, and will be studied by experts before inclusion into the database. Besides providing kinetic information for the interstellar medium, KIDA is planned to contain such data for planetary atmospheres and for circumstellar envelopes. Each year, a subset of the reactions in the database (kida.uva) will be provided as a network for the simulation of the chemistry of dense interstellar clouds with temperatures between 10 K and 300 K. We also provide a code, named Nahoon, to study the time-dependent gas-phase chemistry of zero-dimensional and one-dimensional interstellar sources.